N BUTANOL 99% for synthesis Butan-1-ol
- Part number
- RXSOL-60-6605-047
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
N-butyl alcohol is a colorless liquid. Butan-1-ol is a primary alcohol that is butane in
which a hydrogen of one of the methyl groups is substituted by a hydroxy group
Applications
Butan-1-ol, also known as n-butanol is a primary alcohol with the chemical formula C4H9OH and a linear structure. ... The largest use of 1-butanol is as an industrial intermediate, particularly for the manufacture of butyl acetate (itself an artificial flavorant and industrial solvent).
Dosage and directions
1-Butanol is a hydrophobic molecule, poorly soluble in water, and relatively neutral. 1-Butanol is an alcohol with a 4-carbon structure and the molecular formula of C4H10O.
Characteristics and notes
It is used in plastics, polymers, lubricants, brake fluids, and synthetic rubber. It can be used as a source of fuel. As an environmentally friendly and powerful solvent for cleaning and polishing products. N-Butanol is present in numerous beverages and food and it is used as an artificial food flavoring in the USA.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | RXSOL-60-6605-047 |
| Product Type | n-BUTANOL 99% for synthesis ((Butan-1-ol,) |
| Revised date |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
| Phone | +91 22 27815541 / 42 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com |
Substance / Preparation : 1-Butanol
CAS No :71-36-3
Substance.
Substance name Contents CAS No
1-Butanol : 100 % 71-36-3
Contains no other components or impurities which will influence the classification of the product.
3.1. Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Classification : R10
Xn; R22 R67
Xi; R37/38-41
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008
(CLP) Health hazards : Specific Target Organ Toxicity -
Single exposure - Respiratory tract irritation - Category 3 -
Warning (CLP : STOT SE 3) H335
Specific Target Organ Toxicity - Single exposure - Narcotic effects - Category 3 -
Warning (CLP : STOT SE 3) H336
Skin irritation - Category 2 - Warning (CLP : Skin Corr. 2) H315
Serious eye damage - Category 1 - Danger (CLP : Eye Dam. 1) H318
Acute toxicity, Oral - Category 4 - Warning (CLP : Acute Tox. 4) H302
Physical hazards : Flammable liquids - Category 3 - Warning (CLP : Flam. Liq. 3) H226
3.2. Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s) : Xn : Harmful
R Phrase(s) : R10 : Flammable.
R22 : Harmful if swallowed.
R37/38 : Irritating to respiratory system and skin.
R41 : Risk of serious damage to eyes.
R67 : Vapours may cause drowsiness and dizziness.
S Phrase(s) : S2 : Keep out of the reach of children.
S7/9 : Keep container tightly closed and in well-ventilated place.
S13 : Keep away from food, drink and animal feedingstuffs.
S26 : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39 : Wear suitable gloves and eye/face protection.
S46 : If swallowed seek medical advice immediately and show this container or label.
Labelling Regulation EC 1272/2008 (CLP)
Hazard pictograms
Signal words : Danger
Hazard statements : H226 : Flammable liquid and vapour.
H318 : Causes serious eye damage. H302 : Harmful if swallowed.
H315 : Causes skin irritation. H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness. Precautionary statements
• General : P102: Keep out of reach of children. P103: Read label before use.
P101: If medical advice is needed, have product container or label at hand.
• Prevention : P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical, ventilating, lighting, …, equipment.
P210: Keep away from heat, sparks, open flames or hot surfaces. – No smoking.
P280: Wear protective gloves, protective clothing, eye protection, face protection.
P271: Use only outdoors or in a well-ventilated area.
P261: Avoid breathing dust, fume, gas, mist, vapours, spray.
P233: Keep container tightly closed. P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
• Response : P302+P352: IF ON SKIN : Wash with plenty of soap and water.
P301+P312: IF SWALLOWED : Call a POISON CENTER or doctor if you feel unwell.
P332+P313: If skin irritation occurs : Get medical advice.
P305+P351+P338: IF IN EYES : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P304+P340: IF INHALED : Remove to fresh air and keep at rest in a position comfortable for breathing.
P303+P361+P353: IF ON SKIN (or hair) : Remove immediately all contaminated clothing. Rinse skin with water/shower.
P363: Wash contaminated clothing before reuse.
P370+P378: In case of fire: Use for extinction.
• Storage : P403+P233: Store in well-ventilated place. Keep container tightly closed.
P403+P235: Store in well-ventilated place. Keep cool. P405: Store locked up.
• Disposal considerations : P501: Dispose of this material and its container to hazardous or special
waste collection point, in accordance with local, regional, national and/or international regulation.
3.3. Other hazards
Other hazards : The substance does not fulfil the criteria to be identified as PBT
substance or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : Call a POISON CENTER or doctor if you feel unwell.
Remove to fresh air and keep at rest in a position comfortable for breathing.
Skin contact : Wash with plenty of soap and water.
Specific treatment (see on this label). Get medical advice.
Remove/Take off immediately all contaminated clothing.
If skin irritation occurs : Wash contaminated clothing before reuse.
Eye contact : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor. Ingestion : Obtain emergency medical attention.
Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER or doctor if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Causes serious eye damage. Causes skin irritation.
May cause respiratory irritation. May cause drowsiness or dizziness. Swallowing a small
quantity of this material will result in serious health hazard.
4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person.
If you feel unwell, seek medical advice (show the label where possible).
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products : Under fire conditions, hazardous fumes will be present.
5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection. Special procedures : Exercise caution when fighting
any chemical fire. Avoid (reject) fire-fighting water to enter environment.
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection. Ventilate area
. Avoid breathing dust, fume, gas, mist, vapours, spray.
Technical measures : Use special care to avoid static electric charges.
Special precautions : Remove ignition sources. No naked lights. No smoking.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters.
Notify authorities if product enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Clean up methods : Soak up spills with inert solids, such as clay or diatomaceous
earth as soon as possible. Store away from other materials. Collect spillage.
6.4. Reference to other sections
See section 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Handling : Handle empty containers with care because residual
vapours are flammable. Wash thoroughly after handling.
Take precautionary measures against static discharge. Wash thoroughly after handling.
Use only outdoors or in a wellventilated area. Do not eat, drink or smoke when using this product.
Technical protective measures : Provide good ventilation in process area to prevent formation of vapour.
Proper grounding procedures to avoid static electricity should be followed. Use only non-sparking tools.
Use explosion-proof electrical, ventilating, lighting, …, equipment. Special precautions : No naked lights.
No smoking. Avoid breathing dust, fume, gas, mist, vapours, spray.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place.
Keep in fireproof place. Ground/bond container and receiving equipment.
Keep container tightly closed. Storage - away from : Strong bases.
Strong acids. Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
Specific end use(s) : None.
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure.
• Respiratory protection : Where exposure through inhalation may
occur from use, respiratory protection equipment is recommended.
• Hand protection : Wear protective gloves.
• Skin protection : Wear suitable protective clothing.
• Eye protection : Chemical goggles or safety glasses.
• Others : When using, do not eat, drink or smoke.
8.2. Control parameters
Occupational Exposure Limits : No data available.
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Liquid.
Odour threshold : No data available.
pH value : No data available.
Melting point [°C] : -90 °C
Decomposition point [°C] : N/A
Critical temperature [°C] : N/A
Auto-ignition temperature [°C] : 3430C
Flammability (solid, gas) : Flammable.
Flammable liquid and vapour.
Flash point [°C] : 35 °C
Boiling point [°C] : 116 - 118 °C
Initial boiling point [°C] : 116 °C
Final boiling point [°C] : 118 °C
Evaporation rate : 0,46
Vapour pressure [20°C] : 5 hPa at 20 °C
Vapour pressure mm/Hg : N/A
Vapour density : 2,56
Density [g/cm3] : 0,81
Relative density, gas (air=1) : 0,81
Relative density, liquid (water=1) : N/A
Solubility in water [% weight] : In water,
material soluble. Solubility in water : N/A
Log Pow octanol / water at 20°C : No data available.
Solubility : N/A
Viscosity at 40°C [mm2/s] : N/A
9.2. Other information
Explosive properties : N/A
Explosion limits - upper [%] : 11,20%
Explosion limits - lower [%] : 1,40%
Oxidising properties : No data available.
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established.
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight. Extremely high or low temperatures.
Open flame. Overheating. Heat. Sparks.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes.
Carbon monoxide. Carbon dioxide. May release flammable gases.
11.1. Information on toxicological effects Acute toxicity
• Inhalation : Based on available data, the classification criteria are not met.
• Dermal : Based on available data, the classification criteria are not met.
• Ingestion : Harmful if swallowed. Corrosion : Causes serious eye damage.
Irritation : Causes skin irritation. May cause respiratory irritation.
Sensitization : Based on available data, the classification criteria are not met.
Mutagenicity : Based on available data, the classification criteria are not met.
Carcinogenicity : Based on available data, the classification criteria are not met.
Toxic for reproduction : Based on available data, the classification criteria are not met.
STOT-single exposure : May cause drowsiness or dizziness.
STOT-repeated exposure : Based on available data, the classification criteria are not met.
Aspiration hazard : Based on available data, the classification criteria are not met.
12.1. Toxicity
Toxicity information : Not established.
12.2. Persistence - degradability
Persistence - degradability : Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil
Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance does not
fulfil the criteria to be identified as PBT substance or vPvB substance
according to Annex XIII of Regulation REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment. Dispose in a safe manner
in accordance with local/national regulations. Dispose of this material
and its container to hazardous or special waste collection point, in accordance
with local, regional, national and/or international regulation.
Special precautions : Handle empty containers with care because residual vapours are flammable.
14.1. Land transport (ADR-RID)
Proper shipping name : BUTANOLS
UN N° : 1120
H.I. nr : 30
ADR - Class : 3
Labelling - Transport : 3 : Flammable liquid.
ADR - Classification code : F1
ADR - Group : III
ADR - Packing instructions : P001 R001 LP001
ADR - Limited Quantity : 5 L
ADR - Tunnel code : D/E : Bulk or tank
carriage: Passage forbidden through tunnels of category D and E.
Other carriage: Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : BUTANOLS
UN N° : 1120
IMO-IMDG - Class or division : 3 : Flammable liquid.
IMO-IMDG - Packing group : III
IMO- IMDG - Packing instructions : P001 LP01
IMO-IMDG - Limited quantities : 5 L
IMO-IMDG - Marine pollution : No
EMS-Nr : F-E S-D
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : BUTANOLS
UN N° : 1120
IATA - Class or division : 3 : Flammable liquid.
IATA - Packing group : III
IATA - Passenger and Cargo Aircraft : ALLOWED -
Passenger and Cargo - Packing : 355
instruction - Passenger and Cargo - Maximum : 60 L
Quantity/Packing
IATA - Cargo only : ALLOWED -
Cargo only - Packing instruction : 366 -
Cargo only - Maximum Quantity/ : 220 L
Packing IATA - Limited Quantites : 10 L
ERG-Nr : 3L
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
regulations/legislation specific for the substance or mixture
REACH Restrictions - Annex XVII : The components of this product are not subject to restrictions.
REACH Authorisation - Annex XIV : The components of this product are not subject to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out.
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Further information : None. In accordance with REACH
Regulation (CE) Nº 1907/2006 and with CLP Regulation (CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
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