Strontium Peroxide
- Part number
- RXSOL-19-3254-025
- Category
- Detergent & Soap
- Brand
- RXSOL
Overview
Strontium peroxide appears as a white powder Insoluble in water and slowly decomposed by water Noncombustible but accelerates the burning of combustible material
Applications
Strontium peroxide (SrO2) is an inorganic compound that appears as a white powder and has various applications as an oxidizing agent, antiseptic, and bleaching agent. It is also used in pyrotechnics, for example, to produce a bright red color in fireworks.
Dosage and directions
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | Strontium peroxide |
| Part Number | RXSOL-19-3254-025 |
Company Details:....
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmraine.com |
| Component | CAS No | EC No | Weight % | CLP Classification - Regulation (EC) No1272/2008 |
| Strontium peroxide | 1314-18-7 | EEC No. 215-224-6 | 90-95 |
STOT SE 3 (H335)
Skin Irrit. 2 (H315)
Eye Irrit. 2 (H319)
Ox. Sol. (H272)
|
| REACH registration number |
Classification of the substance or mixture
CLP Classification - Regulation (EC) No 1272/2008
Physical hazards
|
Physical hazards Oxidizing solids |
Category 2 (H272) |
|
Health hazards
Skin Corrosion/Irritation
Serious Eye Damage/Eye Irritation
Specific target organ toxicity - (single exposure)
Skin Corrosion/Irritation
Serious Eye Damage/Eye Irritation
Specific target organ toxicity - (single exposure)
|
2 Skin corrosion/irritation |
|
Environmental hazards
Based on available data, the classification criteria are not met
|
1B Skin sensitization |
Label elements
| Hazard Statements |
H272 - May intensify fire; oxidizer
H315 - Causes skin irritation
H335 - May cause respiratory irritation
H319 - Causes serious eye irritation
|
| Precautionary Statements |
P280 Wear protective gloves and eye protection or face protection.
P261 Avoid breathing mist or vapour or spray.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P210 Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking.
P272 Contaminated work clothing should not be allowed out of the workplace.
P264 Wash contaminated body parts thoroughly after handling.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present andeasy to do. Continue rinsing
|
| Precautionary Statements (Response): |
P312 Call a POISON CENTER or physician if you feel unwell.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for
breathing.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P333 + P313 If skin irritation or rash occurs: Get medical attention.
P332 + P313 If skin irritation occurs: Get medical attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P370 + P378 In case of fire: Use water spray, dry powder, foam, carbon dioxide or
dry sand for extinction.
P312 Call a POISON CENTER or physician if you feel unwell.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for
breathing.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P333 + P313 If skin irritation or rash occurs: Get medical attention.
P332 + P313 If skin irritation occurs: Get medical attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P370 + P378 In case of fire: Use water spray, dry powder, foam, carbon dioxide or
dry sand for extinction.
P312 Call a POISON CENTER or physician if you feel unwell.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for
breathing.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P333 + P313 If skin irritation or rash occurs: Get medical attention.
P332 + P313 If skin irritation occurs: Get medical attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P370 + P378 In case of fire: Use water spray, dry powder, foam, carbon dioxide or
dry sand for extinction.
|
| . Other hazards |
No information available |
Description of first aid measures
| Eye Contact | Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Getmedical attention. |
| Skin Contact | Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Get medical attention. |
| Ingestion | Clean mouth with water. Get medical attention. |
| Inhalation |
Remove from exposure, lie down. Remove to fresh air. If not breathing, give artificial respiration. Get medical attention.
eye specialist.Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an
eye specialist.
|
| Self-Protection of the First Aider | Ensure that medical personnel are aware of the material(s) involved, take precautionstoprotect themselves and prevent spread of contamination.. |
Most important symptoms and effects, both acute and delayed
No information available.
. Indication of any immediate medical attention and special treatment needed
| Notes to Physician | Treat symptomatically |
Extinguishing media
| Suitable extinguishing media | Use extinguishing measures that are appropriate to local circumstances and the surrounding environment |
| Extinguishing media which must not be used for safety reasons | No information available. |
| Special hazards arising from the substance or mixture |
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Oxidizer: Contact with combustible/organic material may cause fire. May ignite combustibles (wood paper, oil, clothing, etc.).
|
| Hazardous Combustion Product |
None under normal use conditions. |
. Advice for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) andfull protective gear
| . Personal precautions, protective equipment and emergency procedures | Ensure adequate ventilation. |
| Environmental precautions | See Section 12 for additional Ecological Information. |
| Methods and material for containment and cleaning up | Sweep up and shovel into suitable containers for disposal. Soak up with inert absorbent material. Keep in suitable, closedcontainers for disposal. Sweep up and shovel into suitable containers for disposal. |
| Reference to other sections | Refer to protective measures listed in Sections 8 and 13 |
|
Precautions for safe handling |
Avoid contact with skin and eyes. Do not breathe dust. Handle product only in closed system or provide appropriate exhaust ventilation. Keep under nitrogen. Keep away from clothing and other combustible materials. |
| Hygiene Measures | Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feedingstuffs. Donot eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, beforere-use. Wash hands before breaks and after work. |
Conditions for safe storage, including any incompatibilities
Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Do not store near combustible materials. Keepundernitrogen. Keep containers tightly closed in a dry, cool and well-ventilated place.
| Technical No substance specific occupational exposure limits known. |
|
Rules for Hazardous Substances (TRGS) 510
Storage Class (LGK) (Germany)
|
Storage Class/LGK 5.1B |
| Switzerland - Storage of hazardous substances | Storage class - SC 5 https://www.kvu.ch/de/themen/stoffe-und-produkte https://www.kvu.ch/fr/themes/substances-et-produits https://www.kvu.ch/it/temi/sostanze-e-prodotti |
| Specific end use(s) | Use in laboratories |
Control parameters
| Exposure limits | This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by theregionspecific regulatory bodies |
| Biological limit values | This product, as supplied, does not contain any hazardous materials with biological limits established by the region specificregulatory bodies |
| Monitoring methods | BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment ofexposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust |
| Derived No Effect Level (DNEL) / Derived Minimum Effect Level (DMEL) | No information available |
| Predicted No Effect Concentration (PNEC) | No information available |
Exposure controls
| Engineering Measures | Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are closetotheworkstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of processorequipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adoptedtocontrol hazardous materials at source |
| Personal protective equipment Eye Protection | Goggles (European standard - EN 166) |
| Hand Protection | Protective gloves |
|
Glove material Breakthrough time Glove thickness EU standard Glove comment Neoprene See manufacturers - EN 374 (minimumrequirement) recommendations |
Skin and body protection
| Skin and body protection |
Wear appropriate protective gloves and clothing to prevent skin exposure. Inspect gloves before use. observe the instructions regarding permeability and breakthrough time which are providedbythesupplier of the gloves. (Refer to manufacturer/supplier for information) gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. gloves with care avoiding skin contamination. |
| Respiratory Protection |
When workers are facing concentrations above the exposure limit they must useappropriate certified respirators. To protect the wearer, respiratory protective equipment must be the correct fit andbeusedand maintained properly |
| Large scale/emergency use |
Use a NIOSH/MSHA or European Standard EN 136 approved respirator if exposurelimitsare exceeded or if irritation or other symptoms are experienced Recommended Filter type: Particulates filter conforming to EN 143 |
| Small scale/Laboratory use |
Use a NIOSH/MSHA or European Standard EN 149:2001 approved respirator if exposurelimits are exceeded or if irritation or other symptoms are experienced. Recommended half mask:- Valve filtering: EN405; or; Half mask: EN140; plusfilter, EN141 When RPE is used a face piece Fit Test should be conducted |
| Environmental exposure controls | No information available |
Information on basic physical and chemical properties
| Physical State | Powder Solid |
| Appearance | Off-white |
| Odour | Odorless |
| Odor Threshold | No data available |
| Melting Point/Range | 215 °C / 419 °F |
| Softening Point | No data available |
| Boiling Point/Range | No information available |
| Flammability (liquid) | Not applicable |
| Flammability (solid,gas) | No information available |
| Explosion Limits | No data available |
| Flash Point |
No information available
materials.Extremely flammable in the presence of the following materials or conditions: oxidizing
materials.
|
| Autoignition Temperature |
No data available |
| Decomposition Temperature | No data available |
| pH | No information available |
| Viscosity | Not applicable |
| Water Solubility | slightly soluble in cold water |
| Solubility in other solvents Partition Coefficient (n-octanol/water | No information available |
| Vapor Pressure | No data available |
| Density / Specific Gravity | No data available |
| Bulk Density | No data available |
| Vapor Density | Not applicable |
| Particle characteristics | No data available |
Other information
| Molecular Formula | O2 Sr |
| Molecular Weight | 119.62 |
| Oxidizing Properties | Oxidizer |
| Evaporation Rate | Not applicable - Solid |
| Reactivity |
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
No corrosive effect on metal.
Oxidizing properties:
Based on its structural properties the product is not classified as oxidizing.
Formation of
flammable gases:
Remarks: Forms no flammable gases in the
presence of water.
|
| Chemical stability | The product is stable if stored and handled as prescribed/indicated. |
| Possibility of hazardous reactions |
Explosion and fire hazard exists under confined conditions. Ignitable air mixtures can form when the
product is heated above the flash point and/or when sprayed or atomized. Formation of explosive
gas/air mixtures.
Risk of spontaneous and violent self-polymerization if inhibitor is lost or product is exposed to
excessive heat. Risk of spontaneous polymerization when heated or in the presence of UV radiation.
With unstabilised product, spontaneous polymerisation may occur e.g. through ambient heat.
Polymerization coupled with heat formation. Polymerization produces gases which may burst closed
or confined containers. Reactions may cause ignition.
Risk of spontaneous polymerization by oxygen depletion of the liquid phase.
Radical formation can cause exothermic polymerization. Reacts with peroxides and other radical
components. Risk of spontaneous polymerization in the presence of starters for radical chain
reactions (e.g. peroxides). Reacts with nitric acid. Polymerizes explosively in contact with strong
oxidizing agents. Risk of spontaneous polymerization in the presence of oxidizing agents.
Hazardous reactions in presence of mentioned substances to avoid.
The product is stabilized against spontaneous polymerization prior to despatch. The product is stable
if stored and handled as prescribed/indicated.
|
| Conditions to avoid |
Avoid heat. Avoid oxygen content above the product of less than 5 %. Do not blanket with nitrogen.
Avoid UV-light and other radiation with high energy. Avoid direct sunlight. Avoid prolonged storage.
Avoid inhibitor loss. Avoid excessive temperatures. |
| Incompatible materials |
radical formers, free radical initiators, peroxides, mercaptans, nitro-compounds, perborates, azides, ether, ketones, aldehydes, amines, nitrates, nitrites, oxidizing agents, reducing agents, strong bases, acid anhydrides, acid chlorides, concentrated mineral acids, metal salts Inert gas
|
| Hazardous decomposition products |
Decomposition products:
Hazardous decomposition products: No hazardous decomposition products if stored and handled as
prescribed/indicated.
Thermal decomposition:
No data available
|
| Primary routes of exposure |
Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. |
| Acute Toxicity/Effects |
Acute toxicity
Assessment of acute toxicity: Of low toxicity after single ingestion. Virtually nontoxic after a single
skin contact. The inhalation of a highly enriched/saturated vapor-air-mixture represents an unlikely
acute hazard.
Oral
Type of value: LD50
Species: rat (male/female)
Value: approx. 4,435 mg/kg (BASF-Test)
Inhalation
Species: rat
Value: (IRT)
Exposure time: 8 h
No mortality within the stated exposition time as shown in animal studies.
Dermal
Type of value: LD50
Species: rabbit (no data)
Value: 7,522 mg/kg
Assessment other acute effects
Assessment of STOT single:
Causes temporary irritation of the respiratory tract.
Irritation / corrosion
Assessment of irritating effects: Not irritating to the eyes. Skin contact causes irritation.
Skin
Species: rabbit
Result: Irritant.
Method: BASF-Test
Information on: 2-ethylhexyl acrylate
Species: rabbit
Result: Irritant.
Method: BASF-Test
Eye
Species: rabbit
Result: non-irritant
Method: OECD Guideline 405
Sensitization
Assessment of sensitization: Sensitization after skin contact possible.
Mouse Local Lymph Node Assay (LLNA)
Species: mouse
Result: sensitizing
Method: OECD Guideline 429
Mouse Local Lymph Node Assay (LLNA)
Species: mouse
Result: sensitizing
Method: OECD Guideline 429
Aspiration Hazard
No aspiration hazard expected.
|
| Chronic Toxicity/Effects |
Repeated dose toxicity
Assessment of repeated dose toxicity: The substance may cause damage to the olfactory epithelium
after repeated inhalation. After repeated exposure the prominent effect is local irritation.
Genetic toxicity
Assessment of mutagenicity: In the majority of studies performed with microorganisms and in
mammalian cell culture, a mutagenic effect was not found. A mutagenic effect was also not observed
in in vivo tests.
Carcinogenicity
Assessment of carcinogenicity: Long-term exposure to highly irritating concentrations resulted in skin
tumors in animals. A carcinogenic effect in humans can be excluded after brief skin contact. IARC
Group 3 (not classifiable as to human carcinogenicity).
Reproductive toxicity
Assessment of reproduction toxicity: The results of animal studies gave no indication of a fertility
impairing effect. The product has not been tested. The statement has been derived from
substances/products of a similar structure or composition.
Teratogenicity
Assessment of teratogenicity: No indications of a developmental toxic / teratogenic effect were seen
in animal studies. The product has not been fully tested. The statements have been derived in parts
from products of a similar structure or composition.
|
| Toxicity |
Aquatic toxicity
Assessment of aquatic toxicity:
Toxic to aquatic life. Harmful to aquatic life with long lasting effects.
Toxicity to fish
LC50 (96 h) 1.81 mg/l, Oncorhynchus mykiss (OECD Guideline 203, semistatic)
The statement of the toxic effect relates to the analytically determined concentration.
Aquatic invertebrates
EC50 (48 h) 1.3 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)
The statement of the toxic effect relates to the analytically determined concentration.
Aquatic plants
EC50 (72 h) 1.71 mg/l (growth rate), Scenedesmus subspicatus (OECD Guideline 201, static)
The statement of the toxic effect relates to the analytically determined concentration.
Chronic toxicity to fish
Study not necessary due to exposure considerations.
Chronic toxicity to aquatic invertebrates
EC10 (21 d) 0.91 mg/l, Daphnia magna (OECD Guideline 211, semistatic)
Assessment of terrestrial toxicity
No effects at the highest test concentration.
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition.
Soil living organisms
Toxicity to soil dwelling organisms:
EC50 (28 d) > 1,000 mg/kg, soil dwelling microorganisms (OECD 217, natural soil)
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition.
Toxicity to terrestrial plants
No data available.
Other terrestrial non-mammals
No data available.
|
| Microorganisms/Effect on activated sludge |
Toxicity to microorganisms
DIN EN ISO 8192 aquatic
activated sludge, domestic/EC20 (30 min): > 1,000 mg/l
Nominal concentration.
|
| Persistence and degradability |
Assessment biodegradation and elimination (H2O)
Readily biodegradable (according to OECD criteria).
Elimination information
70 - 80 % BOD of the ThOD (28 d) (OECD Guideline 301 F) (aerobic, activated sludge, domestic)
Assessment of stability in water
In contact with water the substance will hydrolyse slowly.
Information on Stability in Water (Hydrolysis)
t1/2 18.5 h (25 °C, pH value 11.0), (other, other)
t1/2 210 h (25 °C, pH value 7.0), (other, pH 7)
t1/2 533 h (25 °C, pH value 3.0), (other, other)
|
| Bioaccumulative potential |
Assessment bioaccumulation potential
Does not accumulate in organisms.
Bioaccumulation potential
Bioconcentration factor: 347 (28 d), Cyprinus carpio (OECD-Guideline 305)
Does not accumulate in organisms.
|
| Mobility in soil |
Assessment transport between environmental compartments
The substance will not evaporate into the atmosphere from the water surface.
Adsorption to solid soil phase is not expected.
|
| Waste disposal of substance: | Dispose of in accordance with national, state and local regulations. Do not discharge into drains/surface waters/groundwater. |
| Container disposal: | Uncleaned empties should be disposed of in the same manner as the contents. Flammable vapors may exist in containers in which residues of this product remain. Dispose of in accordance with national, state and local regulations. |
|
Land transport
TDG
|
Not classified as a dangerous good under transport regulations |
|
Sea transport
IMDG
|
Not classified as a dangerous good under transport regulations |
|
Air transport
IATA/ICAO
|
Not classified as a dangerous good under transport regulations |
Federal Regulations
| Registration status: | Chemical DSL, CA released / listed |
| NFPA Hazard codes: | Health: 2 Fire: 2 Reactivity: 2 Special: |
Assessment of the hazard classes according to UN GHS criteria (most recent version):
| Flam. Liq | 4 Flammable liquids |
| STOT SE |
3 (irritating to
respiratory system)
Specific target organ toxicity — single exposure3 (irritating to
respiratory system)
Specific target organ toxicity — single exposure
|
| Skin Corr./Irrit. | 2 Skin corrosion/irritation |
| Aquatic Acute | 2 Hazardous to the aquatic environment - acute |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
