N BUTYL ACETATE AR 99.5%

2.1. Substance: n-BUTYL ACETATE AR

CAS No : 123-86-4

Substance. Contains no other components or impurities which will influence the classification of the product. 

3.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Flammable liquids, H226

Category 3

Specific target organ toxicity — Single exposure, H336

Category 3,

Classification according to Directive 67/548/EEC or 1999/45/EC

Adverse physicochemical, human health and environmental effects

No additional information available

3.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to

displayExtra classification(s) to display

Symbol(s) : Highly flammable

R Phrase(s) : R66: Repeated Exposure may cause skin dryness or cracking.

R67: Vapours may cause drowsiness and dizziness

. R10: Flammable.

S Phrase(s) : S25: Avoid contact with eyes.

Hazard pictogram

Signal word : Warning

Hazard statements : H226 - Flammable liquid and vapour

H336 - May cause drowsiness or dizziness Precautionary statements :

P210 - Keep away from heat/sparks/open flames/hot surfaces. -

No smoking

EUH phrases : EUH066 - Repeated exposure may cause skin dryness or cracking

3.3. Other hazards

No additional information available

4.1. Description of first aid measures

First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a

position comfortable for breathing.

Call a POISON CENTER or doctor/physician if you feel unwell.

First-aid measures after skin contact : Remove/Take off immediately all contaminated

clothing. Rinse skin with water/shower. Repeated exposure may cause skin dryness or

cracking.

First-aid measures after eye contact : Remove contact lenses, if present and easy to do.

Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation

persists: Get medical advice/attention.

First-aid measures after ingestion : Rinse mouth out with water. If you feel unwell, seek

medical advice.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/injuries after inhalation : May cause drowsiness or dizziness.

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically

5.1. Extinguishing media

Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon

dioxide (CO2).

Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture

Fire hazard : Flammable liquid and vapour.

Explosion hazard : May form flammable/explosive vapour-air mixture.

5.3. Advice for firefighters

Protection during firefighting : Do not attempt to take action without suitable protective

equipment.

6.1. Personal precautions, protective equipment and emergency procedures

General measures : Remove ignition sources. Use special care to avoid static electric

charges. No naked lights. No smoking.

6.1.1. For non-emergency personnel

Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Avoid breathing dust/fume/gas/mist/vapours/spray.

Emergency procedures : Stop release.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Collect spillage. Take up liquid spill into absorbent material,

e.g.: sand. Take up mechanically (sweeping, shovelling) and collect in suitable container

for disposal.

6.4. Reference to other sections

No additional information available

9.1. Information on basic physical and chemical properties

Odour threshold : No data available

pH : No data available

Relative evaporation rate (butylacetate=1) : 1

Melting point : -78 °C

Freezing point : No data available

Boiling point : 124 - 126

Flash point : 23 °C

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : Flammable

Flammable liquid and vapour

Vapour pressure : 15 at 25C

Relative vapour density at 20 °C : 4.01

Relative density : No data available

Density : 0.8822 g/cm³

Relative gas density : 0.88

Solubility : Water: 0.7 % @ 20C

Log Pow : 1.82

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidising properties : No data available

Explosive limits : 0.017 - 0.076 vol %

9.2. Other information

No additional information available 

11.1. Information on toxicological effects

Acute toxicity : Not classified

Skin corrosion/irritation : Not classified

Additional information : Repeated exposure may cause skin dryness or cracking

Serious eye damage/irritation : Not classified

Respiratory or skin sensitisation : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

Specific target organ toxicity (single exposure)

: May cause drowsiness or dizziness.

Specific target organ toxicity (repeated exposure) : Not classified

Aspiration hazard : Not classified

12.1. Toxicity

No additional information available

12.2. Persistence and degradability

No additional information available

12.3. Bioaccumulative potential Log Pow 1.82 12.4.

Mobility in soil No

additional information available

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Other adverse effects

No additional information available

13.1. Waste treatment methods

Product/Packaging disposal

Recommendations : Dispose of contents/container to ...

Additional information : Handle empty containers with care because residual vapours are

flammable.

15.1. Safety, health and environmental regulations/legislation specific for the

substance or mixture

15.1.1. EU-Regulations

No REACH Annex XVII restrictions

n-BUTYL ACETATE is not on the REACH Candidate List

n-BUTYL ACETATE is not on the REACH Annex XIV List

15.1.2. National regulations

Germany

AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to

water (Classification according to VwVwS, Annex 2; WGK No 42)

12th Ordinance Implementing the Federal

Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous

Incident Ordinance)

Denmark

Class for fire hazard : Class II-1

Store unit : 5 liter

Classification remarks : R10 ; Emergency management guidelines for the

storage of flammable liquids must be followed

Recommendations Danish Regulation : Young people below the age of 18 years are not

allowed to use the product

15.2. Chemical safety assessment

No additional information available

Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic

vPvB: very persistent and very bioaccumulative

Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN

PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,

labelling and packaging of substances and mixtures, amending and repealing Directives

67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006

Further information : None

. In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation

(CE) Nº 1272/2008

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.