N BUTYLAMINE AR

2.1. Substances: n-BUTYLAMINE AR

CAS-No. : 109-73-9

Substance.

Contains no other components or impurities which will influence the classification of the product  

3.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Flammable liquids, H225 Category 2 Acute toxicity (oral), H302

Category 4 Acute toxicity (dermal), H312

Category 4 Acute toxicity (inhal.), H332

Category 4 Skin corrosion/irritation, H314

Category 1A Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]

Adverse physicochemical, human health and environmental effects

No additional information available

3.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]

Extra labelling to displayExtra classification(s) to display

Symbol(s) : Xi : Irritation Highly flammable 

R Phrase(s) : R36/37/38: Irritating to eyes, respiratory system and skin.

R20/21/22 : Harmful by inhalation, in contact with skin and if swallowed.

R11: Highly flammable. S Phrase(s) : S16: Keep away from source of  ignition-No smoking.

S26: In the case of contact with eyes, rinse immediately with plenty of water and seek medical advise.

S29: Do not empty into drains.

Hazard pictograms: 

Signal word : Danger

Hazard statements : H225 - Highly flammable liquid and vapour.

H302+H312+H332 - Harmful if swallowed, in contact with skin or if inhaled

H314 - Causes severe skin burns and eye damage.

Precautionary statements  : P210 - Keep away from heat, hot surfaces,

sparks, open flames and other ignition sources. No smoking.

P280 - Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing.

P310 - Immediately call a POISON CENTER/doctor

3.3. Other hazards

4.1. Description of first aid measures

First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing.

Immediately call a POISON CENTER/doctor. Specific treatment is urgent (see supplemental first aid instruction on this label).

First-aid measures after skin contact : Rinse skin with water/shower.

Take off immediately all contaminated clothing. Immediately call a POISON CENTER/doctor.

Specific measures (see supplemental first aid instruction on this label).

Wash with plenty of water/…. Wash contaminated clothing before reuse.

First-aid measures after eye contact : Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.

Specific treatment (see supplemental first aid instruction on this label).

First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER/doctor if you feel unwell. Do NOT induce vomiting.

Immediately call a POISON CENTER/doctor. Specific treatment (see supplemental first aid instruction on this label).

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/effects : Causes severe skin burns and eye damage. Symptoms/effects after

inhalation : Corrosive to the respiratory tract. Symptoms/effects after

skin contact : Repeated exposure to this material can result in absorption

through skin causing significant health hazard. Harmful in contact with

skin. Symptoms/effects after eye contact : Causes serious eye damage.

Symptoms/effects after ingestion : Swallowing a small quantity of this material will result in serious health hazard.

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically. 

 

5.1. Extinguishing media

Suitable extinguishing media : dry chemical powder, alcohol-resistant foam,

carbon dioxide (CO2). Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture

Fire hazard : Highly flammable liquid and vapour.

Explosion hazard : May form flammable/explosive vapour-air mixture.

5.3. Advice for firefighters

Protection during firefighting : Do not attempt to take action without suitable protective equipment. 

6.1. Personal precautions, protective equipment and emergency procedures 

General measures : Remove ignition sources.

Use special care to avoid static electric charges. No open flames. No smoking.

6.1.1. For non-emergency personnel

Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Use personal protective equipment as required.

Emergency procedures : Stop release.

6.2. Environmental precautions Avoid

release to the environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Collect spillage. On land, sweep or shovel

into suitable containers. Soak up spills with inert solids, such as clay

or diatomaceous earth as soon as possible.

6.4. Reference to other sections

No additional information available 

9.1. Information on basic physical and chemical properties

Odour threshold : 0.08

ppm pH : 13

Relative evaporation rate (butylacetate=1) : 7.3

Melting point : -49.1 °C

Freezing point : No data available

Boiling point : 77.1 °C

Flash point : -120 °C

Auto-ignition temperature : 3120 °C

Decomposition temperature : No data available

Flammability (solid, gas) : Extremely

flammable Highly flammable liquid and vapour.

Vapour pressure : 82 mm Hg at 20C

Relative vapour density at 20 °C : 2.5

Relative density : No data available

Density : 0.74 g/cm³

Solubility : Water: Miscible in water

Log Pow : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidising properties : No data available

Explosive limits : 0.017 - 0.098 vol %

9.2. Other information

No additional information available 

11.1. Information on toxicological effects

Acute toxicity : Oral: Harmful if swallowed.

Dermal: Harmful in contact with skin.

Inhalation: Harmful if inhaled.

Skin corrosion/irritation : Causes severe skin burns and eye damage.

pH: 13 Serious eye damage/irritation : Serious eye damage,

category 1, implicit pH: 13

Respiratory or skin sensitisation : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

STOT-single exposure : Not classified

Additional information : Corrosive to the respiratory tract.

STOT-repeated exposure : Not classified

Aspiration hazard : Not classified

Potential adverse human health effects

and symptoms : Harmful if swallowed. Harmful in contact with skin. 

12.1. Toxicity

No additional information available

12.2. Persistence and degradability

No additional information available

12.3. Bioaccumulative potential

No additional information available

12.4. Mobility in soil

No additional information available

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Other adverse effects 

No additional information available 

13.1. Waste treatment methods

Product/Packaging disposal recommendations : Dispose of contents/container to

hazardous or special waste collection point, in accordance with local, regional,

national and/or international regulation. Additional information : Handle empty

containers with care because residual vapours are flammable. 

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1. EU-Regulations No REACH Annex XVII restrictions n-BUTYLAMINE AR is not on the

REACH Candidate List n-BUTYLAMINE AR is not on the REACH Annex XIV List

15.1.2. National regulations

Germany Reference to AwSV : Water hazard class (WGK) 1,

low hazard to water (Classification according to AwSV; ID No. 44)

12th Ordinance Implementing the Federal

Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)

Netherlands

SZW-lijst van kankerverwekkende stoffen : The substance is not listed

SZW-lijst van mutagene stoffen : The substance is not listed

NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Borstvoeding : The substance is not listed

NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Vruchtbaarheid : The substance is not listed

NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Ontwikkeling : The substance is not listed

Denmark

Classification remarks : Emergency management guidelines for the storage of flammable

liquids must be Followed Recommendations Danish Regulation : Young people below the age of

18 years are not allowed to use the product Pregnant/breastfeeding women working with the product

must not be in direct contact with the product

15.2. Chemical safety assessment

No additional information available 

Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vPvB: very persistent and very bioaccumulative

Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL

of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives

67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Further information : None. In accordance with REACH

Regulation (CE) Nº 1907/2006 and with CLP Regulation (CE) Nº 1272/2008 

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.