Allyl Chloride
A clear colorless liquid with an unpleasant pungent odor.
- Part number
- RXSOL-60-1221-500
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
Allyl chloride is the organic compound with the formula CH2=CHCH2Cl. This colorless liquid is insoluble in water but soluble in common organic solvents.
Applications
A clear colorless liquid with an unpleasant pungent odor. Flash point -20°F. Boiling point 113°F. Less dense than water (7.8 lb / gal) and insoluble in water.
Dosage and directions
ALLYL CHLORIDE is highly flammable when exposed to heat, flame or oxidizing agents. Polymerizes violently and exothermically with Lewis acids (aluminum chloride, boron trifluoride, sulfuric acid) or metals (aluminum, magnesium, zinc, or galvanized metal). Incompatible with acids (nitric acid, chlorosulfonic acid, oleum), with strong bases (sodium hydroxide, potassium hydroxide), with ethyleneimine and ethylenediamine. Attempts to alkylate benzene or toluene using allyl chloride in the presence of ethylaluminum chlorides have led to explosions
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | Allyl Chloride |
| Part Number | RXSOL-60-1221-500 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmraine.com |
Substances
| Synonyms |
3-Chloro-1-propene
Chlorallylene
|
| Formula | C3H5Cl |
| Molecular weight | 76,52 g/mol |
| CAS-No. | 107-05-1 |
| EC-No. | 203-457-6 |
| Index-No. | 602-029-00-X |
| Component | Classification | Concentration |
| 3-chloropropene | ||
|
CAS-No. 107-05-1
EC-No. 203-457-6
Index-No. 602-029-00-X
|
Flam. Liq. 2; Acute Tox. 4;
Skin Irrit. 2; Eye Irrit. 2;
Muta. 2; Carc. 2; STOT SE
3; STOT RE 2; Aquatic
Acute 1; H225, H302,
H332, H312, H315, H319,
H341, H351, H335, H373,
H400
|
<= 100 % |
Classification of the substance or mixture
| Flammable liquids, (Category 2) |
H225: Highly flammable liquid and vapor.
|
| Acute toxicity, (Category 4) | H302: Harmful if swallowed. |
| Acute toxicity, (Category 4) | H332: Harmful if inhaled. |
| Acute toxicity, (Category 4) | H312: Harmful in contact with skin. |
| Skin irritation, (Category 2) | H315: Causes skin irritation. |
| Eye irritation, (Category 2) | H319: Causes serious eye irritation. |
|
Germ cell mutagenicity,
(Category 2)
|
H341: Suspected of causing genetic defects. |
| Carcinogenicity, (Category 2) | H351: Suspected of causing cancer. |
|
Specific target organ toxicity -
single exposure, (Category 3),
Respiratory system
|
H335: May cause respiratory irritation. |
|
Specific target organ toxicity -
repeated exposure, (Category 2),
Nervous system, Liver, Kidney
|
H373: May cause damage to organs
through prolonged or repeated exposure.
|
|
Short-term (acute) aquatic
hazard, (Category 1)
|
H400: Very toxic to aquatic life |
Label elements
| Signal Word | Danger |
| Hazard Statements |
H225 Highly flammable liquid and vapor.
H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H341 Suspected of causing genetic defects.
H351 Suspected of causing cancer.
H373 May cause damage to organs (Nervous system, Liver, Kidney) through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
|
| Precautionary Statements |
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
|
| Supplemental Hazard Statements | None |
| Reduced Labeling (<= 125 ml) | |
| Signal Word | Danger |
| Hazard statement |
H341 Suspected of causing genetic defects.
H351 Suspected of causing cancer.
|
| Precautionary statement |
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
|
| Supplemental Hazard Statements | None |
| Other hazards |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Ecological information:
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Toxicological information:
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
|
| General Advice | Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen. |
| In case of skin contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician. |
| In case of eye contact | After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses. |
| If swallowed | After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. |
| Most important symptoms and effects, both acute and delayed | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Suitable extinguishing media | Carbon dioxide (CO2) Foam Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture |
Carbon oxides
Hydrogen chloride gas
Combustible.
Pay attention to flashback.
Vapors are heavier than air and may spread along floors.
Development of hazardous combustion gases or vapours possible in the event of fire.
Forms explosive mixtures with air at ambient temperatures.
|
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Further information | Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
| Personal precautions, protective equipment and emergency procedures |
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition.
Evacuate the danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
|
| Environmental precautions | Do not let product enter drains. Risk of explosion. |
| Methods and material for containment and cleaning up | Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area. |
| Reference to other sections | For disposal see section 13. |
Precautions for safe handling
| Advice on safe handling | Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. |
| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
| Hygiene measures |
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
For precautions see section 2.2.
|
| Conditions for safe storage, including any incompatibilities | |
| Storage conditions |
Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition.
|
| Storage stability | Recommended storage temperature 2 - 8 °C |
| Storage Class | Storage class (TRGS 510): 3: Flammable liquids |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
Control parameters
Ingredients with workplace control parameters
Exposure controls
Personal protective equipment
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
| Skin protection |
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Full contact
Material: Viton®
Minimum layer thickness: 0,7 mm
Break through time: 480 min
Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M)
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: butyl-rubber
Minimum layer thickness: 0,7 mm
Break through time: 30 min
Material tested: Butoject® (KCL 898)
|
| Body Protection |
Flame retardant antistatic protective clothing.
|
| Respiratory protection |
Required when dusts are generated.
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Recommended Filter type: Filter type P2
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
|
| Control of environmental exposure | Do not let product enter drains. Risk of explosion |
| Physical state | Clear, liquid |
| Color | Light yellow |
| Odor | Pungent |
| Melting point/freezing point | Melting point/range: -130 °C - lit. |
| Initial boiling point and boiling range | 44 - 46 °C - lit. |
| Flammability (solid, gas) | No data available |
| Upper/lower flammability or explosive limits |
Upper explosion limit: 11,2 %(V)
Lower explosion limit: 3,2 %(V)
|
| Flash point | ca.-32 °C |
| Autoignition temperature | No data available |
| Decomposition temperature | No data available |
| pH | No data available |
| Viscosity |
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
|
| Water solubility | ca.4 g/l at 25 °C |
| Partition coefficient: n-octanol/water | log Pow: 2,1 at 25 °C - Bioaccumulation is not expected |
| Vapor pressure | ca.398 hPa at ca.20 °C |
| Density | 0,939 g/cm3 at 25 °C - lit. |
| Relative density | No data available |
| Relative vapor density | No data available |
| Particle characteristics | No data available |
| Explosive properties | No data available |
| Oxidizing properties | None |
| Other safety information | |
| Relative vapor density | 2,64 - (Air = 1.0) |
| Reactivity |
Vapors may form explosive mixture with air.
|
| Chemical stability | The product is chemically stable under standard ambient conditions (room temperature) |
| Possibility of hazardous reactions |
Violent reactions possible with:
Peroxides
Strong oxidizing agents
Alkali metals
Alkaline earth metals
Zinc
acids
Risk of explosion with:
sodium
Potassium
Violent polymerization may be caused by:
iron(III) compounds
boron trifluoride
Aluminum
aluminium chloride
conc. sulfuric acid
|
| Conditions to avoid | Warming |
| Incompatible materials | No data available |
| Hazardous decomposition products | In the event of fire: see section 5 |
| Acute toxicity |
LD50 Oral - Rat - female - 419 mg/kg
(OECD Test Guideline 401)
Acute toxicity estimate Oral - 419 mg/kg
(ATE value derived from LD50/LC50 value)
Acute toxicity estimate Inhalation - 4 h - 10,1 mg/l - vapor
(Expert judgment)
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Acute toxicity estimate Dermal - 1.100,1 mg/kg
(Expert judgment)
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
|
| Skin corrosion/irritation |
Remarks: Causes skin irritation.
Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
|
| Serious eye damage/eye irritation |
Remarks: Causes serious eye irritation.
Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Remarks: Lacrimal irritation due to vapours.
|
| Respiratory or skin sensitization |
Local lymph node assay (LLNA) - Mouse
Result: negative
(OECD Test Guideline 429)
|
| Germ cell mutagenicity |
Suspected of causing genetic defects.
Test Type: Genotoxicity in vivo
Species: Drosophila melanogaster
Application Route: inhalation (vapor)
Method: OECD Test Guideline 477
Result: negative
|
| Carcinogenicity | Suspected of causing cancer. |
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure | May cause respiratory irritation. - Respiratory Tract |
| Specific target organ toxicity - repeated exposure |
May cause damage to organs through prolonged or repeated exposure.
- Nervous system, Liver, Kidney
|
| Aspiration hazard | No data available |
| Additional Information | |
| Endocrine disrupting properties Product: | |
| Assessment |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
RTECS: UC7350000
spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
|
| Toxicity | |
| Toxicity to algae |
Static test NOEC - Scenedesmus quadricauda (Green algae) - 6,3
mg/l - 8 d
(DIN 38412)
|
| Toxicity to bacteria |
Remarks: (ECHA)
(3-chloropropene)
|
| Toxicity to fish(Chronic toxicity) |
Semi-static test NOEC - Poecilia reticulata (guppy) - 1,2 mg/l - 14 d
(OECD Test Guideline 204)
|
| Persistence and degradability | |
| Biodegradability |
aerobic - Exposure time 28 d
Result: 95 % - Readily biodegradable.
(OECD Test Guideline 301C)
|
| Ratio BOD/ThBOD |
25 %
Remarks: (External MSDS)
|
| Bioaccumulative potential | No data available |
| Mobility in soil | No data available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties Product | |
| Assessment | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher |
| Other adverse effects | No data available |
| Waste Treatment Methods | No data available |
| UN number | ADR/RID: 1100 IMDG: 1100 IATA: 1100 |
| UN proper shipping name |
ADR/RID: ALLYL CHLORIDE
IMDG: ALLYL CHLORIDE
IATA: Allyl chloride
|
| Transport hazard class(es) | ADR/RID: 3 (6.1) IMDG: 3 (6.1) IATA: 3 (6.1) |
| Packaging group | ADR/RID: l IMDG: l IATA: l |
| Environmental hazards | ADR/RID: yes IMDG Marine pollutant: yes IATA: no |
| Special precautions for user | |
| Tunnel restriction code | (C/E) |
| Further information | No data available |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
|
Authorisations and/or restrictions on use
National legislation
Seveso III: Directive 2012/18/EU of the
European Parliament and of the Council
on the control of major-accident hazards
involving dangerous substances.
|
E1 ENVIRONMENTAL HAZARDS
P5c FLAMMABLE LIQUIDS
|
| Other regulations |
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable.
Take note of Dir 94/33/EC on the protection of young people at work.
|
| Chemical Safety Assessment | For this product a chemical safety assessment was not carried out |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
