D Limonene
- Part number
- RXSOL-41-8347-025
- Category
- Medicine
- Brand
- RXSOL
Overview
D'Limonene is obtained as a product of the citrus. It is the major component of the oil extracted from the rinds of citrus fruits. D'Limonene is lighter than water, and is usually colorless This product has a boiling range of 310-352 degrees Fahrenheit. It has a flash point of 119 degrees Fahrenheit and is considered a combustible liquid. It is not soluble in water. Depending on the composition, d-limonene can dissolve in solvents and surfactants.
Technical specifications
Limonene is a clear, colourless liquid at room temperature with an extremely strong smell of Oranges. Limonene is a chiral molecule.
Physical Properties
| Colour | Clear |
| Appearance | Colorless |
| Specific Gravity @25 °C | 0.841 ±0.03 |
| Water solubility | Immiscible |
| Optical Rotation @25 °C | +96° to +104° |
| Flash Point, Closed Cup |
>43 °C [>110 °F] |
Applications
D-Limonene Solvent - 98 % Adhesive Remover, Asbestos shingle remover, Bathroom cleaner, Car wash, Carpet stain cleaner, Concrete cleaner (used in warehouse floor scrubbers or for cleaning oils and greases off concrete pads and parking structures), Cosmetic applications, Electronics cleaning, engine degreaser (automotive, aircraft, and aerospace industries), Floor cleaner, Fragrance additive, Graffiti remover, Grease trap maintainer, Hand cleaner, Heat transfer medium, Industrial odor control applications, Kitchen cleaner, Laundry pre-spotter, Lift station and sewage treatment applications, Marine vessel cleaner, Metal cleaner (industrial), Parts cleaner, Printing press cleaner, Recycling applications, Tar/asphalt remover, Tile remover, Wheel cleaner, Window cleaner. d'Limonene is also a possible candidate for a variety of medical applications including cancer and Aids research, and has been been noted to have insecticidal properties.
Dosage and directions
D-Limonene Solvent can be chnged as water dilutable and rinsable solution, d'Limonene must first be combined with a surfactant. These products are mostly used in household and institutional settings in place of caustic and other water-based cleaners. Both pre-diluted solutions of d'Limonene/surfactant or concentrated solutions which need to be diluted before use can be made. The use concentrations of d-limonene are usually 5-15%. Usually these solutions are used as wipe cleaners or as a spray. It can also be used in industrial settings where a water rinse for parts washing is desired to remove any residue which may remain.
Characteristics and notes
Safety & Precaution :
Solvent-resistant gloves should be worn when working with d-limonene. The best gloves to use are Nitrile, although Viton and polyethylene film gloves will work. d'Limonene has been classified as a slight skin irritant, because it can remove naturally occurring oils from the skin. This has not been shown to cause lasting damage.
Used straight, d-limonene can cause a certain amount of swelling of polymers, so any plastic materials must be chosen carefully. This includes equipment seals made of rubber, such as Buna-N, EPDM (ethylene-propylene diene terpolymer) or Neoprene. It is compatible with Viton. It can delaminate carpet backing. d'Limonene is biodegradable, but due to its low flash point, it must be treated as hazardous waste for disposal.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | D Limonene |
| Part Number | RXSOL-41-8347-025 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmraine.com |
Substances
| Synonyms |
(+)-Carvene
(+)-p-Mentha-1,8-diene
(R)-4-Isopropenyl-1-methyl-1-cyclohexene
|
| Formula | C10H16 |
| Molecular weight | 136,23 g/mol |
| CAS-No. | 5989-27-5 |
| EC-No. | 227-813-5 |
| Index-No. | 601-029-00-7 |
| Component | Classification | Concentration |
| (R)-(+)-limonene | ||
|
CAS-No. 5989-27-5
EC-No. 227-813-5
Index-No. 601-096-00-2
|
Flam. Liq. 3; Skin Irrit. 2;
Skin Sens. 1; Asp. Tox. 1;
Aquatic Acute 1; Aquatic
Chronic 1; H226, H315,
H317, H304, H400, H410
M-Factor - Aquatic Acute:
1 - Aquatic Chronic: 1
|
<= 100 % |
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification of the substance or mixture
| Flammable liquids, (Category 3) |
H226: Flammable liquid and vapor.
|
| Skin irritation, (Category 2) | H315: Causes skin irritation |
| Skin sensitization, (Category 1) | H317: May cause an allergic skin reaction. |
| Aspiration hazard, (Category 1) | H304: May be fatal if swallowed and enters airways. |
|
Short-term (acute) aquatic
hazard, (Category 1)
|
H400: Very toxic to aquatic life |
|
Long-term (chronic) aquatic
hazard, (Category 1)
|
H410: Very toxic to aquatic life with long lasting effects. |
Label elements
| Signal Word | Danger |
| Hazard Statements |
H226 Flammable liquid and vapor.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H410 Very toxic to aquatic life with long lasting effects.
|
| Precautionary Statements |
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P331 Do NOT induce vomiting.
|
| Supplemental Hazard Statements | None |
| Reduced Labeling (<= 125 ml) | |
| Signal Word | Danger |
| Hazard Statements |
H317 May cause an allergic skin reaction.
H304 May be fatal if swallowed and enters airways.
|
| Precautionary Statements |
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P331 Do NOT induce vomiting.
|
| Supplemental Hazard Statements | None |
| Other hazards |
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
Ecological information:
The substance/mixture does not contain components considered to have endocrine
disrupting properties according to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Toxicological information:
The substance/mixture does not contain components considered to have endocrine
disrupting properties according to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
|
| General Advice | Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalation: fresh air. |
| In case of skin contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician. |
| In case of eye contact | After eye contact: rinse out with plenty of water. Remove contact lenses. |
| If swallowed | After swallowing: caution if victim vomits. Risk of aspiration! Keep airways free. Pulmonary failure possible after aspiration of vomit. Call a physician immediately. |
| Most important symptoms and effects, both acute and delayed | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Suitable extinguishing media | Carbon dioxide (CO2) Foam Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture |
Carbon oxides
Combustible.
Vapors are heavier than air and may spread along floors.
Forms explosive mixtures with air at elevated temperatures.
Development of hazardous combustion gases or vapours possible in the event of fire.
|
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Further information | Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
| Personal precautions, protective equipment and emergency procedures |
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition.
Evacuate the danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
|
| Environmental precautions | Do not let product enter drains. Risk of explosion. |
| Methods and material for containment and cleaning up | Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area. |
| Reference to other sections | For disposal see section 13. |
Precautions for safe handling
| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
| Hygiene measures |
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
For precautions see section 2.2.
|
| Conditions for safe storage, including any incompatibilities | |
| Storage conditions | Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. |
| Storage class | Storage class (TRGS 510): 3: Flammable liquids |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
| Skin protection |
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Material tested:KCL 741 Dermatril® L
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Material tested: KCL 741 Dermatril® L
|
| Body Protection | Flame retardant antistatic protective clothing. |
| Respiratory protection |
Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic
compounds
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
|
| Control of environmental exposure | Do not let product enter drains. Risk of explosion. |
| Physical state | Liquid, clear |
| Color | Colorless |
| Odor | Characteristic |
| Melting point/freezing point | Melting point/range: -73,97 °C - OECD Test Guideline 102 |
| Initial Boiling Point and Boiling range | 176 - 177 °C |
| Flammability (solid, gas) | No data available |
| Upper/lower flammability or explosive limits |
Upper explosion limit: 6,1 %(V)
Lower explosion limit: 0,7 %(V)
|
| Flash point | 51 °C - closed cup |
| Autoignition temperature | 245 °C at 995,44 hPa |
| Decomposition temperature | No data available |
| pH | No data available |
| Viscosity |
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
|
| Water solubility | 0,00569 g/l at 20 °C - OECD Test Guideline 105 |
| Partition coefficient: n-octanol/water | log Pow: 4,38 at 37 °C - Potential bioaccumulation |
| Vapor pressure | 2 hPa at 24,85 °C |
| Density | 0.842 g/mL at 20 °C |
| Relative density | 0.8400 - 0.8440 at 20 °C |
| Relative vapor density | 4,70 - (Air = 1.0) |
| Particle characteristics | No data available |
| Explosive properties | No data available |
| Oxidizing properties | None |
| Other safety information | |
| Relative vapor density | 4,70 - (Air = 1.0) |
| Reactivity | Vapor/air-mixtures are explosive at intense warming. |
| Chemical stability | The product is chemically stable under standard ambient conditions (room temperature) |
| Possibility of hazardous reactions |
Violent reactions possible with:
Strong oxidizing agents
acids
|
| Conditions to avoid | Heating |
| Incompatible materials | No data available |
| Hazardous decomposition products | In the event of fire: see section 5 |
| Acute toxicity |
LD50 Oral - Rat - male and female - > 2.000 mg/kg
(OECD Test Guideline 423)
Inhalation: No data available
LD50 Dermal - Rabbit - > 5.000 mg/kg
Remarks: (RTECS)
|
| Skin corrosion/irritation |
Skin - Rabbit
Result: Mild skin irritation - 4 h
(OECD Test Guideline 404)
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
|
| Serious eye damage/eye irritation |
Eyes - Rabbit
Result: No eye irritation
(OECD Test Guideline 405)
|
| Respiratory or skin sensitization |
Local lymph node assay (LLNA) - Mouse
Result: May cause sensitization by skin contact.
(OECD Test Guideline 429)
|
| Germ cell mutagenicity |
Test Type: In vitro mammalian cell gene mutation test
Test system: mouse lymphoma cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative
Test Type: sister chromatid exchange assay
Test system: Chinese hamster ovary cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 479
Result: negative
Test Type: Ames test
Test system: S. typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
Test Type: Chromosome aberration test in vitro
Test system: Chinese hamster ovary cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 473
Result: negative
Test Type: comet assay
Species: Rat
Application Route: Oral
Result: negative
|
| Carcinogenicity | This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification. |
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure | No data available |
| Specific target organ toxicity - repeated exposure | No data available |
| Aspiration hazard | Aspiration may cause pulmonary edema and pneumonitis. |
| Additional Information | |
| Endocrine disrupting properties Product | |
| Assessment |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Repeated dose toxicity - Mouse - male and female - NOAEL (No observed adverse effect level) - 1.650 mg/kg - LOAEL (Lowest observed adverse effect level) - 3.300 mg/kg
RTECS: GW6360000
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Liver - Irregularities - Based on Human Evidence
|
| Toxicity | |
| Toxicity to fish |
flow-through test LC50 - Pimephales promelas (fathead minnow) -
0,72 mg/l - 96 h
(OECD Test Guideline 203)
|
|
Toxicity to daphnia
and other aquatic
invertebrates
|
semi-static test EC50 - Daphnia magna (Water flea) - 0,307 mg/l -
48 h
(OECD Test Guideline 202)
|
| Toxicity to algae |
static test ErC50 - Pseudokirchneriella subcapitata (green algae) -
0,32 mg/l - 72 h
(OECD Test Guideline 201)
static test EC10 - Pseudokirchneriella subcapitata (green algae) -
0,174 mg/l - 72 h
(OECD Test Guideline 201)
|
| Toxicity to bacteria |
EC50 - Sludge Treatment - 3,94 mg/l
(OECD Test Guideline 209)
Remarks: (External MSDS)
|
|
Toxicity to daphnia
and other aquatic
invertebrates(Chronic
toxicity)
|
semi-static test NOEC - Daphnia magna (Water flea) - 0,08 mg/l -
21 d
(OECD Test Guideline 211)
|
| Persistence and degradability | The methods for determining the biological degradability are not applicable to inorganic substances. |
| Bioaccumulative potential | No data available |
| Mobility in soil | No data available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties Product | |
| Assessment | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects | Discharge into the environment must be avoided. |
| Waste Treatment Methods | |
| Product | See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
| UN number | ADR/RID:2052 IMDG: 2052 IATA: 2052 |
| UN proper shipping name |
ADR/RID: DIPENTENE
IMDG: DIPENTENE
IATA: Dipentene
|
| Transport hazard class(es) | ADR/RID:3 IMDG: 3 IATA:3 |
| Packaging group | ADR/RID: III IMDG: III IATA: III |
| Environmental hazards | ADR/RID: no IMDG Marine pollutant: no IATA: no |
| Special precautions for user | No data available |
| Further information | Not classified as dangerous in the meaning of transport regulations. |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Other regulations | Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | A Chemical Safety Assessment has been carried out for this substance. |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
Availability
D'limonene exporter and supplier in Muscat, Barka, Sohar, Oman, Fujairah, UAE Middle East, Sharjah, Abudhabi, Dubai, Mumbai, Nashik, Navi mumbai, Gandhidham, Surat, Chennai, Kolkata, Visakhapatnam, Patna, Tata, Ranchi, Sudan, Nairobi Kenya
