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Cooling Water Chemical

HEDP 60%

Chelating agent, Scale and Corrosion Inhibitor. Scale prevention and corrosion inhibition in water treatment.
Part number
RXSOL-81-8160-250
Brand
RXSOL
HEDP 60%

Overview

HEDP ACID chemical name is Hydroxy Ethylidene -1,1-Diphosphonic acid manufacturer, supplier and exporter. HEDP is  organophosphonate compound which have chemical properties of sequestration, deflocculation, threshold inhibition and hydrolytic stability etc. HEDP is an organophosphoric acid corrosion inhibitor. It can chelate with Fe, Cu, and Zn ions to form stable chelating compounds. It can dissolve the oxidized materials on these metals’ surfaces.

Technical specifications

Specifications of HEDP 60%
Chemical Name1 Hydroxy ethylidene 1,1-diphosphonic Acid or HEDP 60% Synonyms : 1-Hydroxyethylidene-1,1- Diphosphonic Acid
CAS No809-21-4
Molecular Weight/ Molecular Formula : C2H8O7P
AppearanceClear / pale yellow Solution
Active Content+ 2%
Specific gravity @ 25°C1.42 –1.4
pH (1% solution)Less than
Chlorides as HCl< 0.01 %
Phosphorous acid< 2.5 %
Acetic acid< 0.5 %
Iron Content (ppm)<
SolubilitySoluble in water
Assay%
Chelation Value5

Applications

RXSOL-81-8160-250 chemically having wide range of applications including scale prevention and corrosion inhibition in water treatment. 

Hydroxy Ethylidene -1,1-Diphosphonic acid is organophosphonate with multifunctional properties like sequestration, deflocculation, threshold inhibition and hydrolytic stability, as a single active ingredient. Because of the combination of these properties Hydroxy Ethylidene -1,1-Diphosphonic acid has a wide range of applications. One of the most important applications is in scale prevention and corrosion inhibition in water treatment. 
HEDP is used as scale and corrosion inhibition in circulating cool water system, oil field and low-pressure boilers in fields such as electric power, chemical industry, metallurgy, fertilizer, etc.. In light woven industry, HEDP is used as detergent for metal and nonmetal. In dyeing industry, HEDP is
used as peroxide stabilizer and dye-fixing agent; In non-cyanide electroplating.

Dosage and directions

HEDP is used as chelating agent. The dosage of 1-10mg/L is preferred as scale inhibitor, 10-50mg/L as corrosion inhibitor, and 1000-2000mg/L as detergent. Usually, HEDP is used together with polycarboxylic acid. It is used as a strong chelating agent for metal ions like Ca, Mg & Fe in water treatment, textile applications. Its efficient inhibition for CaCO3 & CaSO4 alone or in combination with low molecular weight polymers. Very effective in protecting metal corrosion. HEDP also having very strong chlorine stability. 

Characteristics and notes

Storage for ten months in room shady and dry place. Safety Protection: Acidity, Avoid contact with eye and skin, once contacted, flush with water. 

Safety and SDS

Read the safety data sheet before handling. Wear suitable gloves and eye protection.

View safety data sheet
Product Name HEDP 60%
Product Type RXSOL-81-8160-250

Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Stock Point : Mumbai, Kandla, Kolkata, Chennai, Visakhapatnam, Fujairah

Phone +91 22 27815541 / 42
Fax +91 22 2781 1318 :::AOH :0091 9821214367
Email rxsolchemicals@gmail.com
 Chemical % TWAEV / TLV
ppm / mg/m3
LD50
ORAL
(mg/kg)
SKIN
LC50 ppm
INHALATION
HEDP 58-62% Not listed  2400 >7940 not known
Canada – WHMIS  Key:

D 2B, E
B 2 – Flash Point <38oC, B 3 – Flash Point >38oC &<93oC
D 1 – Immediately Toxic, D 2 – Chronic Toxicity
C – Oxidising Substance, E - Corrosive

U.S.A. – HMIS  Key: Health – 2, Fire – 0, Reactivity – 1
0=minimal, 1=slight, 2=moderate, 3=serious, 4=severe

3. (b) HAZARDS – TOXICITY:

Effects, Acute Exposure:

Skin Contact Irritating, may be corrosive if not removed promptly
Skin Absorption                       Slight; no toxic effects likely by this route
Eye Contact Irritating, may be corrosive if not removed promptly
Inhalation Product mist is irritating; prolonged exposure may be corrosive to respiratory tract
Ingestion Irritating to mouth, throat & stomach – not a route of industrial exposure

Effects, Chronic Exposure:

General Chronic ingestion of HEDP binds to bone, reducing mineralization of bone in adult beagles & in young rats giving rise to less calcium (& presumably strength) in bone
Sensitising Not a sensitiser in humans or animals
Carcinogen/Tumorigen     Not considered a tumorigen or a carcinogen in humans or animals
Reproductive Effect Reduced fertility in rats on prolonged ingestion; no known effect in humans
Mutagen No known effect on humans or animals; some mutagenic effect observed in onion & barley root tips – significance of this to human health is not known
Synergistic With Not known
LD50 (oral) 2400, 3130 & 3550mg/kg (rat)
LD50 (skin) >7940mg/kg (rabbit), >10,000mg/kg (rabbit)
LC50 (inhalation) Not known
 SKIN: Wash with plenty of water. Remove contaminated clothing and do not reuse until thoroughly laundered.
 EYES: Wash eyes with plenty of water, holding eyelids open. Seek medical assistance promptly if there is irritation.
 INHALATION:            Remove from contaminated area promptly. CAUTION: Rescuer must not endanger himself! If breathing stops, administer artificial respiration and seek medical aid promptly.
 INGESTION: Give plenty of water to dilute product, or milk if available to neutralise it. Do not induce vomiting (NOTE below). Keep victim quiet. If vomiting occurs, lower victim’s head below hips to prevent inhalation of vomited material. Seek medical help promptly.
Inadvertent inhalation of vomited material may seriously damage the lungs. The danger of this is greater than the risk of poisoning through absorption of this relatively low-toxicity substance. The stomach should only be emptied under medical supervision, and after the installation of an airway to protect the lungs.
Flash Point Not known – will not flash
Autoignition Temperature Not known – will not burn
Flammable Limits Not known – will not burn
Combustion Products Nitrogen oxides, phosphorous oxides
Firefighting Precautions As for materials sustaining fire; firefighters must wear SCBA
Static Charge Accumulation Cannot accumulate a static charge on agitation or pumping
Leak Precaution dyke to control spillage and prevent environmental contamination Handling Spill ventilate contaminated area; recover free liquid with suitable corrosion resistant pumps; absorb residue on an inert sorbent, sweep, shovel, & store in closed containers for recycling or disposal
above 0oC / 32oF. Do not use steel containers. Suitable containers include polyethylene, polypropylene, fibreglass, glass-lined steel and polyvinyl chloride. Do not use copper or brass plumbing or valves. Ensure that containers, whether empty or full, or part full, are tightly sealed unless in use. Avoid creating or breathing product mist. Use with adequate exhaust ventilation if a mist is created. Never cut, drill, weld or grind on or near this container. Avoid all contact with skin and wash work clothes frequently. An eye bath and safety shower must be available near the workplace.
 
ACGIH TLV         Not listed
OSHA PEL Not listed
STEL Not listed
Ventilation No special mechanical ventilation required
Hands Nitrile gloves recommended – other types may also protect; consult supplier to confirm suitability
Eyes Safety glasses with side shields; a face shield is also recommended – always protect the eyes
Clothing Wear impermeable (above) apron, boots, & long sleeves if there is any danger of splashing,
Odour & Appearance Clear, colourless or yellowish liquid with slight odour
Odour Threshold Not known
Vapour Pressure 17.5mmHg / 2.3kPa (20oC / 68oF) – only water vapour present
Evaporation Rate (Butyl Acetate = 1) As for water
Vapour Density (air = 1) 0.6 – only water vapour present
Boiling Range 108oC / 226oF
Freezing Point <0oC / <32oF
Specific Gravity 1.44 (20/20oC)
Water Solubility Complete
Also soluble in Methanol, ethylene glycol – probably other polar solvents
Viscosity Not known
pH <2
Molecular Weight 206grams per mole
Dangerously Reactive With Strong oxidising agents, strong reducing agents, strong alkalis, amines
Also Reactive With Corrodes some base metals; releases toxic gases in contact with metal sulphides & sulphites
Stability Stable; will not polymerize
Decomposes in Presence of Not known
Decomposition Products None apart from Hazardous Combustion Products
Sensitive to Mechanical Impact           No
Canada DSL On inventory
U.S.A. TSCA On inventory
Europe EINECS On inventory
China IECS On inventory
Europe Risk Phrases              R: 22, 36, 38 – harmful if swallowed, irritating to eyes, irritating to skin
Europe Safety Phrases S: 13, 24-26, 36, 46 – keep away from food, drink and animal feed, avoid contact with skin, avoid contact with eyes, in case of contact with eyes, rinse immediately & seek medical advice, wear suitable protective clothing, if swallowed, seek medical advice immediately
Bioaccumulation This product is not a bioaccumulator
Biodegradation HEDP degrades in the presence of oxygen at a wide range of rates – 0% - 48% in 28 days (a dozen test reports) In Europe, considered to be “readily biodegradeable”
Abiotic Degradation          12-17% in 11 days degradation by direct photolysis
Mobility in soil, water This product is water soluble and will move readily in soil and water

Aquatic Toxicity:

LC50 (Fish, 96hr) 2180mg/litre (Pimephelas promelas & Cyprinodon variegatus), 200-368mg/litre (Salmo gairdneri),695mg/litre (Ictalurus punctatus), 868mg/litre (Lepomis macrochirus), 207 & 350mg/l (Leuciscus idus)
EC50 (Crustacea, 24hr)       527mg/litre (Daphnia magna), 1770mg/litre (Palaemonetes pugio)
EC50 (Algae) 39mg/litre (Selenastrum capricornutum)

   

Waste Disposal     Do not flush to sewer, recycle if possible, biodegradation in approved facility with bacterial sludge of “proven effectiveness” (see Part 12, below) for HEDP is preferred
Containers Drums should be reused. Recondition and pressure test by a licensed reconditioner prior to re-use.
Pails must be vented and thoroughly dried prior to crushing and recycling.
IBCs (intermediate bulk containers): polyethylene bottle must be pressure tested & recertified at 30 months.
Replace at 60 months (5yrs). Steel containers must be inspected, pressure tested & recertified every 5 years.
Never cut, drill, weld or grind on or near this container, even if empty
Canada TDG
AND
U.S.A. 49 CFR 
 PIN UN-3265
Shipping Name corrosive liquid, acidic, N.O.S. (1hydroxyethanediphosphonic acid)
  Class 8
Packing Group III

Marine Pollutant not a marine pollutant

 No informtion Available

The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in terms of safety requirements and does not signify any warranty with regard to the product's properties The data given here only applies when product used for proper application(s). The product is not sold as suitable for other applications usage in such may cause risks not mentioned in this sheet. Do not use for other application(s) without seeking advice from manufacturer.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.


 

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