N BROMOSUCCINIMIDE
- Part number
- RXSOL-60-6605-046
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
N-bromosuccinimide (NBS) is used as a highly specific bromination agent both in free-radical
substitutions and in electrophilic additions of unsaturated systems, because releases small quantities of bromine.
Applications
N-Bromosuccinimide (NBS) is a brominating and oxidizing agent that is used as source for bromine in radical reactions (for example: allylic brominations) and various electrophilic additions.
Dosage and directions
N-Bromosuccinimide or NBS is a chemical reagent used in radical substitution, electrophilic addition, and electrophilic substitution reactions in organic chemistry.
Characteristics and notes
NBS is used as a substitute for Br2 in these cases since Br2 tends to react with double bonds to form dibromides. The advantage of NBS is that it provides a low-level concentration of Br2, and bromination of the double bond doesn't compete as much.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name |
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| Product Type | N-BROMOSUCCINIMIDE | |||
| Revised date |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
| Phone | +91 22 27815541 / 42 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com |
2.1 Substances : N-BROMOSUCCINIMIDE
CAS-No. : 128-08-5
Substance.
Contains no other components or impurities which will influence the classification of the
product.
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Skin corrosion/irritation, H314
Category 1B
Acute toxicity (oral), H302
Category 4
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Xn; R22
C; R34
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to
displayExtra classification(s) to display
Symbol(s) : Xi : Irritation.
Xn: Harmful
R Phrase(s) : R22:Harmful if swallowed.
R36/37/38: Irritating to eyes, respiratory system and skin.
S Phrase(s) : S26:In the case of contact with eyes, rinse immediately with plenty of water
and seek medical advise.
S36: Wear suitable protective clothing.
Hazard pictograms
Signal word: Danger
Hazard statements : H302 - Harmful if swallowed.
H314 - Causes severe skin burns and eye damage.
Precautionary statements : P280 - Wear protective gloves, protective clothing, eye
protection, face protection
. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P310 - Immediately call a POISON CENTER or doctor.
3.3. Other hazards
No additional information available
4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for
breathing. Immediately call a POISON CENTER/doctor.
First-aid measures after skin contact : Take off immediately all contaminated clothing.
Rinse skin with water/shower.
Immediately call a POISON CENTER/doctor.
First-aid measures after eye contact : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a
POISON CENTER/doctor.
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER/doctor if you
feel unwell. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects : Causes severe skin burns and eye damage.
Symptoms/effects after ingestion : Harmful if swallowed
. 4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
No additional information available
5.3. Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment,
including respiratory protection.
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : On land, sweep or shovel into suitable containers. Soak up
spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes. Do not breathe vapours.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and
other exposed areas with mild soap and water before eating, drinking or smoking and
when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 175 - 180 °C
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : 6.1
Relative density : No data available
Density : 2.098 g/cm³
Solubility : Water: 1.47 (gm / 100 gm water)
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
10.1. Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid
Air contact. Direct sunlight. Moisture.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.
11.1. Information on toxicological effects
Acute toxicity : Oral: Harmful if swallowed.
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/irritation : Serious eye damage, category 1,
implicit Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed.
12.1. Toxicity
No additional information available
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available.
13.1. Waste treatment methods
Product/Packaging disposal
Recommendations : Dispose of contents/container to hazardous or special waste
collection point, in accordance with local, regional, national and/or international
regulation.
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 3261
UN-No. (IMDG) : 3261
UN-No. (IATA) : 3261
UN-No. (ADN) : 3261
UN-No. (RID) : 3261
14.2. UN proper shipping name
Proper Shipping Name (ADR) : CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Proper Shipping Name (IMDG) : CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Proper Shipping Name (IATA) : Corrosive solid, acidic, organic, n.o.s.
Proper Shipping Name (ADN) : CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Proper Shipping Name (RID) : CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Transport document description (ADR) : UN 3261 CORROSIVE SOLID, ACIDIC,
ORGANIC, N.O.S., 8, III, (E)
Transport document description (IMDG) : UN 3261 CORROSIVE SOLID, ACIDIC,
ORGANIC, N.O.S., 8, III
Transport document description (IATA) : UN 3261 Corrosive solid, acidic, organic,
n.o.s., 8, III
Transport document description (ADN) : UN 3261 CORROSIVE SOLID, ACIDIC,
ORGANIC, N.O.S., 8, III
Transport document description (RID) : UN 3261 CORROSIVE SOLID, ACIDIC,
ORGANIC, N.O.S., 8, III
14.3. Transport hazard class(es)
ADR- Transport hazard class(es) (ADR) : 8
Danger labels (ADR) : 8
\IMDG- Transport hazard class(es) (IMDG) : 8
Danger labels (IMDG) : 8
IATA- Transport hazard class(es) (IATA) : 8
Hazard labels (IATA) : 8
ADN- Transport hazard class(es) (ADN) : 8
Danger labels (ADN) : 8
RID- Transport hazard class(es) (RID) : 8
Danger labels (RID) : 8
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
Overland transport Classification code (ADR) : C4
Special provisions (ADR) : 274
Limited quantities (ADR) : 5kg
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P002, IBC08, LP02, R001
Special packing provisions (ADR) : B3
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container instructions (ADR) : T1
Portable tank and bulk container special provisions (ADR) : TP33
Tank code (ADR) : SGAV, L4BN
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage – Bulk (ADR) : VC1, VC2, AP7
Hazard identification number (Kemler No.) : 80
Orange plates : Tunnel restriction code (ADR) : E
EAC code : 2X
Transport by sea Special provisions (IMDG) : 223, 274
Packing instructions (IMDG) : P002, LP02
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B3
Tank instructions (IMDG) : T1
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : A
Properties and observations (IMDG) : Causes burns to skin, eyes and mucous
membranes.
MFAG-No : 154
Air transport PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y845
PCA limited quantity max net quantity (IATA) : 5kg
PCA packing instructions (IATA) : 860
PCA max net quantity (IATA) : 25kg
CAO packing instructions (IATA) : 864
CAO max net quantity (IATA) : 100kg
Special provisions (IATA) : A3, A803
ERG code (IATA) : 8L
Inland waterway transport Classification code (ADN) : C4
Special provisions (ADN) : 274
Limited quantities (ADN) : 5 kg
Excepted quantities (ADN) : E1
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
Rail transport Classification code (RID) : C4
Special provisions (RID) : 274
Excepted quantities (RID) : E1
Packing instructions (RID) : P002, IBC08, LP02, R001
Special packing provisions (RID) : B3
Mixed packing provisions (RID) : MP10
Portable tank and bulk container instructions (RID) : T1
Portable tank and bulk container special provisions (RID) : TP33
Tank codes for RID tanks (RID) : SGAV, L4BN
Transport category (RID) : 3
Special provisions for carriage – Bulk (RID) : VC1, VC2, AP7
Colis express (express parcels) (RID) : CE11
Hazard identification number (RID) : 80
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
N-BROMOSUCCINIMIDE is not on the REACH Candidate List
N-BROMOSUCCINIMIDE is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 3, severe hazard to water (Classification
according to
AwSV; ID No. 7246)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous
Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen – Borstvoeding : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen –
Vruchtbaarheid : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen – Ontwikkeling : The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not
allowed to use the product
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
Availability
[N BROMOSUCCINIMIDE] manufacturers, suppliers, exporters in Mumbai, Gandhidham, Kolkata, Varanasi, Visakhapatnam, Chennai, Fujairah, Dubai, Canada BC, Barka, Sohar, Muscat, Oman.
Lab chemicals manufacturers, suppliers, exporters in India, UAE Middle East, Barka, Sohar, Muscat, Oman, Canada.
[N BROMOSUCCINIMIDE] is available in small packing as well as in bulk. Buy premium quality [N BROMOSUCCINIMIDE] and other lab chemicals from one of the most trusted brands.
