HEXA METHYL PHOSPHORIC ACID TRIIAMIDE HMPA

2.1. Substance : HEXAMETHYLPHOSPHORIC ACID TRIAMIDE (HMPA)

CAS No : 680-31-9

Substance.

Contains no other components or impurities which will influence the classification of the

product

3.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Germ cell mutagenicity, H340

Category 1B

Carcinogenicity, H350

Category 1A

Classification according to Directive 67/548/EEC or 1999/45/EC

Adverse physicochemical, human health and environmental effects

No additional information available

3.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to

displayExtra classification(s) to display

Symbol(s) : T : Very toxic

R Phrase(s) : R45: May cause cancer.

R46: May Cause heritable genetic damage.

S Phrase(s) : S53: Avoid exposure – obtain special instruction before use.

S45: In case of accident or if you feel unwell, seek medical advice immediately (show the

label where possible)

. Hazard pictograms

Signal word : Danger

Hazard statements : H340 - May cause genetic defects

H350 - May cause cancer

Precautionary statements : P201 - Obtain special instructions before use

P308+P313 - IF exposed or concerned: Get medical advice/attention

3.3. Other hazards

No additional information available 

4.1. Description of first aid measures

First-aid measures after inhalation : Get medical advice/attention. Remove person to fresh

air and keep comfortable for breathing.

First-aid measures after skin contact : Wash with plenty of soap and water.

First-aid measures after eye contact : Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing.

First-aid measures after ingestion : Rinse mouth. Get medical advice/attention.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/injuries : May cause genetic defects. May cause cancer.

4.3. Indication of any immediate medical attention and special treatment needed

No additional information available 

5.1. Extinguishing media

Suitable extinguishing media : Water spray. Foam. Dry powder. Carbon dioxide.

Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture

No additional information available

5.3. Advice for firefighters

Protection during firefighting : Do not attempt to take action without suitable protective

equipment.

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Use personal protective equipment as required.

Emergency procedures : Ventilate area.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous

earth as soon as possible. On land, sweep or shovel into suitable containers. Collect

spillage.

6.4. Reference to other sections

No additional information available

9.1. Information on basic physical and chemical properties

Odour threshold : No data available

pH : No data available

Relative evaporation rate (butylacetate=1) : No data available

Melting point : No data available

Freezing point : No data available

Boiling point : No data available

Flash point : No data available

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapour pressure : No data available

Relative vapour density at 20 °C : No data available

Relative density : No data available

Solubility : No data available

Log Pow : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidising properties : No data available

Explosive limits : No data available

9.2. Other information

No additional information available

11.1. Information on toxicological effects

Acute toxicity : Not classified

Skin corrosion/irritation : Not classified

Serious eye damage/irritation : Not classified

Respiratory or skin sensitisation : Not classified

Germ cell mutagenicity : May cause genetic defects.

Carcinogenicity : May cause cancer.

Reproductive toxicity : Not classified

Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated exposure) : Not classified

Aspiration hazard : Not classified

12.1. Toxicity

No additional information available

12.2. Persistence and degradability

No additional information available

12.3. Bioaccumulative potential

No additional information available

12.4. Mobility in soil

No additional information available

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Other adverse effects

No additional information available

13.1. Waste treatment methods

No additional information available

15.1. Safety, health and environmental regulations/legislation specific for the

substance or mixture

15.1.1. EU-Regulations

No REACH Annex XVII restrictions

HEXAMETHYLPHOSPHORIC ACID TRIAMIDE is not on the REACH Candidate List

HEXAMETHYLPHOSPHORIC ACID TRIAMIDE is not on the REACH Annex XIV

List 15.

1.2. National regulations

Germany

12th Ordinance Implementing the Federal

Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous

Incident Ordinance)

Denmark

Recommendations Danish Regulation : Young people below the age of 18 years are not

allowed to use the product

Pregnant/breastfeeding women working with the product must not be in direct

contact with the product

The requirements from the Danish Working Environment Authorities regarding work

with carcinogens must be followed during use and disposal

15.2. Chemical safety assessment

No additional information available

Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.

vPvB: very persistent and very bioaccumulative

Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN

PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,

labelling and packaging of substances and mixtures, amending and repealing Directives

67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006

Further information : None.

In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation

(CE) Nº 1272/2008 

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.